Conclusions
The rate constants for the addition of triethylsilyl radicals to α-phenyl-N-tert-butylnitrone (kadd=(11±5)·106 liter/mole·sec) and 2,4,6-tri-tert-butylnitrosobenzene (kadd= (1.5±0.3)·109 liter/mole·sec) at ∼20°C were determined by the EPR method.
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Literature cited
R. Kh. Freidlina, I. I. Kandror, and R. G. Gasanov, Usp. Khim.,47, 508 (1978).
R. G. Gasanov, L. V. Ivanova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1011 (1982).
S. Terabe and R. Konaka, J. Chem. Soc. Perkin Trans.,2, 369 (1973).
H. Chaudra, I. M. Davidson, and M. C. R. Symons, J. Chem. Soc. Perkin Trans.,2, 1353 (1982).
E. Janzen and C. Evans, J. Am. Chem. Soc.,94, 8236 (1972);95, 8205 (1973).
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano, J. Am. Chem. Soc.,104, 5123 (1982).
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano, J. Am. Chem. Soc.,104, 5119 (1982).
R. G. Gasanov and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,235, 1309 (1977).
E. G. Janzen and B. J. Blackburn, J. Am. Chem. Soc.,91, 4481 (1969).
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano, J. Am. Chem. Soc.,105, 3292 (1983).
J. Copper, A. Hudson, and R. A. Jackson, J. Chem. Soc. Perkin Trans.2, 1933 (1973).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 938–941, April, 1984.
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Gasanov, R.G., Ivanova, L.V. & Freidlina, R.K. Rate constants for addition of triethylsilyl radicals to spin traps. Russ Chem Bull 33, 864–867 (1984). https://doi.org/10.1007/BF00947858
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DOI: https://doi.org/10.1007/BF00947858