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Formation of complex Cu(III) ions using organic peroxides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The biuret complexes of Cu(II) when treated with 2-methyltetrahydro-2-furyl peroxide in water are converted to diamagnetic Cu(III) compounds.

  2. 2.

    The biuret complexes of Cu(II) and Cu(III) are efficient catalysts for the decomposition of organic hydroperoxides and H2O2 in water at room temperature.

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Literature cited

  1. Yu. V. Il'in, V. A. Plakhotnik, V. G. Glukhovtsev, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 2243 (1982).

  2. R. Ripan and I. Chetyanu, Inorganic Chemistry, Chemistry of Metals [Russian translation], Vol. 2, Mir, Moscow (1972), p. 721.

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  4. V. G. Glukhovtsev and G. I. Zaitseva, Zh. Organ. Khim.,15, 625 (1979).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Yu. V. Il'in, V. G. Glukhovtsev, M. I. Trofimov & G. I. Nikishin

Authors
  1. Yu. V. Il'in
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  2. V. G. Glukhovtsev
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  3. M. I. Trofimov
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  4. G. I. Nikishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 933–935, April, 1984.

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Il'in, Y.V., Glukhovtsev, V.G., Trofimov, M.I. et al. Formation of complex Cu(III) ions using organic peroxides. Russ Chem Bull 33, 859–861 (1984). https://doi.org/10.1007/BF00947856

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  • DOI: https://doi.org/10.1007/BF00947856

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