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Synthesis and some properties of tetra[η5-cyclopentadienyldi-carbonylrheniummercury]

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The previously unknown [η5-C5H5Re(CO)2Hg]4, η5-C5H5Re(CO)2(HgI)2, and η5-C5H5Re-(CO)2(HgBr)2 were synthesized by us. The structure of [η5-C5H5Re(CO)2Hg]4 was established by RSA. The [η5-C5H5Re(CO)2Hg]4 molecule has an unusual tetrameric structure with alternating Hg atoms and cis-[η5-C5H5Re(CO)2] fragments.

  2. 2.

    The reaction of the complexes [η5-C5H5Re(CO)2Hg]4 and [η5-C5H5Re(CO)2HG·1/3C6H6]4 with I2, Br2, MeCOOH, Me3I, PPh3, and HCl was studied.

  3. 3.

    The complexes η-C5H5Re(CO)2 (HgBr)2 and η5-C5H5Re(CO)2 (HgI)2 are reduced by NaBH4 to η5-C5H5Re(CO)2H2.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. E. Kolobova, Z. P. Valueva, E. I. Kazimirchuk, V. G. Andrianov & Yu. T. Struchkov

Authors
  1. N. E. Kolobova
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  2. Z. P. Valueva
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  3. E. I. Kazimirchuk
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  4. V. G. Andrianov
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  5. Yu. T. Struchkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp, 920–923, April, 1984.

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Kolobova, N.E., Valueva, Z.P., Kazimirchuk, E.I. et al. Synthesis and some properties of tetra[η5-cyclopentadienyldi-carbonylrheniummercury]. Russ Chem Bull 33, 847–850 (1984). https://doi.org/10.1007/BF00947851

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  • DOI: https://doi.org/10.1007/BF00947851

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