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New method for the synthesis of 1,4-enynes by the cross-coupling of magnesium acetylides with allyl compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A method was developed for the synthesis of 1,4-enynes by the cross-coupling of compounds of type (RC≡C)2Mg and RC≡CMgBr with allyl alcohol derivatives using Ni(acac)2-Ph3P as the catalyst.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 907–908, April, 1984.

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Dzhemilev, U.M., Ibragimov, A.G., Saraev, R.A. et al. New method for the synthesis of 1,4-enynes by the cross-coupling of magnesium acetylides with allyl compounds. Russ Chem Bull 33, 835–836 (1984). https://doi.org/10.1007/BF00947846

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  • DOI: https://doi.org/10.1007/BF00947846

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