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Hindered rotation of unsubstituted amino groups of fluorinated β-aminovinyl thiones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The hindered rotation of the unsubstituted amino group around the N-C= bond in fluorinated β-aminovinyl thiones with a gem arrangement of the RF and NH2 groups was established.

  2. 2.

    The activation parameters of this process are but slightly dependent on the nature of RF and increase when two RF groups are inserted.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Urals Scientific Center, Academy of Sciences of the USSR, Sverdlovsk

    K. I. Pashkevich, I. G. Busygin, A. L. Nikol'skii & V. A. Gindin

  2. A. A. Zhdanov Leningrad State University, USSR

    K. I. Pashkevich, I. G. Busygin, A. L. Nikol'skii & V. A. Gindin

Authors
  1. K. I. Pashkevich
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  2. I. G. Busygin
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  3. A. L. Nikol'skii
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  4. V. A. Gindin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 904–906, April, 1984.

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Pashkevich, K.I., Busygin, I.G., Nikol'skii, A.L. et al. Hindered rotation of unsubstituted amino groups of fluorinated β-aminovinyl thiones. Russ Chem Bull 33, 832–834 (1984). https://doi.org/10.1007/BF00947845

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  • DOI: https://doi.org/10.1007/BF00947845

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