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Silylotropy in substituted 2-triethylsiloxyphenoxyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Some unsymmetrically substituted o-semiquinolate complexes, containing the triethylsilyl group, were obtained.

  2. 2.

    The thermodynamic parameters of the equilibrium between various forms of the obtained radicals, which are realized during the migration of the triethylsilyl group, were determined.

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Literature cited

  1. A. I. Prokof'ev and T. I. Prokof'eva, Dokl. Akad. Nauk SSSR,210, 361 (1973).

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  2. A. L. Buchachenko and A. M. Vasserman, Stable Radicals [in Russian], Khimiya, Moscow (1973).

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  3. J. Wertz and J. Bolton, Theory and Practical Application of the EPR Method [Russian translation], Mir, Moscow (1975).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. K. Chekalov, A. I. Prokof'ev, A. A. Khodak, N. N. Bubnov, S. P. Solodovnikov, A. A. Zhdanov & M. I. Kabachnik

Authors
  1. A. K. Chekalov
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  2. A. I. Prokof'ev
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  3. A. A. Khodak
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  4. N. N. Bubnov
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  5. S. P. Solodovnikov
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  6. A. A. Zhdanov
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  7. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 898–901, April, 1984.

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Chekalov, A.K., Prokof'ev, A.I., Khodak, A.A. et al. Silylotropy in substituted 2-triethylsiloxyphenoxyls. Russ Chem Bull 33, 827–830 (1984). https://doi.org/10.1007/BF00947843

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  • DOI: https://doi.org/10.1007/BF00947843

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