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Transformations of steroids communication 135. Improved method of synthesis of 16,17α-epiminopregnenolone with a corticoid side chain

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Replacement of the 21-acetate group in 3β,21-diacetoxypregna-5,16-dien-20-one by a tetrahydropyranyl group leads to reaction with S,S-diphenylsulfimine with formation of the 16,17α-aziridine.

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Literature cited

  1. A. V. Kamernitskii (Kamernitzky), A. M. Turuta, Z. I. Istomina, and B. S. Él'yanov, Synthesis, 509 (1982).

  2. A. V. Kamernitskii, Z. I. Istomina, A. M. Turuta, T. M. Fadeeva, and B. S. Él'yanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2383 (1982).

  3. N. Furukawa, T. Yoshimura, M. Ohtsu, T. Akasaka, and S. Oae, Tetrahedron,36, 73 (1980).

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  4. T. Yoshimura, T. Akasaka, N. Furukawa, and S. Oae, Heterocycles,7, 287 (1977).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, Z. I. Istomina, A. M. Turuta, B. S. Él'yanov & A. A. Korobov

Authors
  1. A. V. Kamernitskii
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  2. Z. I. Istomina
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  3. A. M. Turuta
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  4. B. S. Él'yanov
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  5. A. A. Korobov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 893–895, April, 1984.

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Kamernitskii, A.V., Istomina, Z.I., Turuta, A.M. et al. Transformations of steroids communication 135. Improved method of synthesis of 16,17α-epiminopregnenolone with a corticoid side chain. Russ Chem Bull 33, 821–824 (1984). https://doi.org/10.1007/BF00947841

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  • DOI: https://doi.org/10.1007/BF00947841

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