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Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with benzene and cyclohexane

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Upon irradiation of phosphine hydride complexes of molybdenum and tungsten in benzene or cyclohexane, the products from photochemical dehydrogenation of the complexes are capable of abstracting hydrogen from the solvents, the molybdenum compounds being more reactive than the analogous tungsten complexes.

  2. 2.

    A decrease in the irradiation wavelength increases the efficiency of interaction of MH4L4 with the solvents.

  3. 3.

    Complexes with monodentate ligands are more reactive than complexes containing bidentate ligands.

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Literature cited

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Authors and Affiliations

  1. Chernogolovka Branch, Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    A. P. Pivovarov, L. M. Ioffe, Yu. V. Gak & Yu. G. Borod'ko

Authors
  1. A. P. Pivovarov
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  2. L. M. Ioffe
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  3. Yu. V. Gak
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  4. Yu. G. Borod'ko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 762–764, April, 1984.

The authors wish to express their appreciation to V. D. Makhaev and A. P. Borisov for kindly furnishing the samples of the phosphine hydride complexes.

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Pivovarov, A.P., Ioffe, L.M., Gak, Y.V. et al. Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with benzene and cyclohexane. Russ Chem Bull 33, 700–702 (1984). https://doi.org/10.1007/BF00947817

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  • DOI: https://doi.org/10.1007/BF00947817

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