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A pulse radiolysis study of the reactivity of Cl2 and Br2 relative to vanadyl ions in aqueous solution

  • A. V. Gogolev
  • I. E. Makarov
  • A. K. Pikaev
Brief Communications
  • 18 Downloads

Conclusions

  1. 1.

    The rate constants of the reactions of vanadium(IV) ions with Cl2 and Br2 ions were measured by pulse radiolysis in acidic aqueous solution.

     
  2. 2.

    These rate constants increase with increasing acidity. This effect is attributed to “equalization” of the vanadium(IV) and vandium(V) ion species in strongly acidic media.

     

Keywords

Aqueous Solution Acidity Vanadium Acidic Medium Acidic Aqueous Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. V. Gogolev, I. E. Makarov, and A. K. Pikaev, Izv. Akad. Nauk SSSR, Ser. Khim., 1419 (1984).Google Scholar
  2. 2.
    A. K. Pikaev, S. A. Kabakchi, I. E. Makarov, and B. G. Ershov, Pulse Radiolysis and Its Applications [in Russian], Atomizdat, Moscow (1980), p. 182.Google Scholar
  3. 3.
    J. Nagypal, J. Fabian, and R. E. Connick, Acta Chim. Acad. Sci. Hung.,110, 447 (1982).Google Scholar
  4. 4.
    V. V. Lukachina, A. T. Pilipenko, and O. N. Karpova, Zh. Neorg. Khim.,22, 1275 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • A. V. Gogolev
    • 1
  • I. E. Makarov
    • 1
  • A. K. Pikaev
    • 1
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRMoscow

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