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Oxidation of dicarbadodecahydronidoundecaborate anions by mercuric chloride in tetrahydrofuran and pyridine

  • L. I. Zakharkin
  • V. N. Kalinin
  • G. G. Zhigareva
Brief Communications

Conclusions

It was found that mercuric chloride has a specific oxidative effect on the anions of dicarbadodecahydronidoundecaborates in THF or pyridine, which consists in the preferential replacement of hydride hydrogen by the ligand in the 8 position of the anion.

Keywords

Oxidation Hydrogen Chloride Pyridine Hydride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    D. C. Young, D. V. Home, and H. F. Hawthorne, J. Am. Chem. Soc.,91, 859 (1969).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • V. N. Kalinin
    • 1
  • G. G. Zhigareva
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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