Oxidation of dicarbadodecahydronidoundecaborate anions by mercuric chloride in tetrahydrofuran and pyridine
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It was found that mercuric chloride has a specific oxidative effect on the anions of dicarbadodecahydronidoundecaborates in THF or pyridine, which consists in the preferential replacement of hydride hydrogen by the ligand in the 8 position of the anion.
KeywordsOxidation Hydrogen Chloride Pyridine Hydride
- 1.D. C. Young, D. V. Home, and H. F. Hawthorne, J. Am. Chem. Soc.,91, 859 (1969).Google Scholar