Reaction of α-bromo ketones with bis(triethylsilyl)- and bis(triethylgermyl)mercury

  • D. V. Gendin
  • O. A. Kruglaya
  • I. D. Kalikhman
  • N. S. Vyazankin
  • G. G. Furin
Brief Communications

Conclusions

1. The reaction of bis (triethylsilyl)mercury with α-bromoacetophenone, its halo-substituted derivatives, and 1-bromo-1-phenyl-2-propanone gave the corresponding triethylsilyl ethers of enols. In the case of bis(triethylgermyl)mercury, depending on the employed α-bromo ketone, either the enol ether or a mixture of the O- and C-germylation products is formed.

Keywords

Ether Mercury Ketone Enol Enol Ether 

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Literature cited

  1. 1.
    J. K. Rasmussen, Synthesis,1971, 91.Google Scholar
  2. 2.
    R. Fields, R. N. Haszeldine, and R. E. Hutton, J. Chem. Soc.,C 1967, 2559.Google Scholar
  3. 3.
    C. Eaborn, R. A. Jackson, and R. W. Walsingham, J. Chem. Soc.,C 1967, 2188.Google Scholar
  4. 4.
    N. S. Vyazankin, G. A. Razuvaev, and E. N. Gladyshev, Dokl. Akad. Nauk SSSR,155, 830 (1964).Google Scholar
  5. 5.
    O. A. Kruglaya, Yu. I. Baukov, B. I. Petrov, and N. S. Vyazankin, Zh. Obshch. Khim.,41, 1408 (1971).Google Scholar
  6. 6.
    I. F. Lutsenko, Yu. I. Baukov, I. Yu. Belavin, and A. N. Tvorogov, J. Organomet. Chem.,14, 229 (1968).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • D. V. Gendin
    • 1
  • O. A. Kruglaya
    • 1
  • I. D. Kalikhman
    • 1
  • N. S. Vyazankin
    • 1
  • G. G. Furin
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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