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Reaction of α-bromo ketones with bis(triethylsilyl)- and bis(triethylgermyl)mercury

  • D. V. Gendin
  • O. A. Kruglaya
  • I. D. Kalikhman
  • N. S. Vyazankin
  • G. G. Furin
Brief Communications

Conclusions

1. The reaction of bis (triethylsilyl)mercury with α-bromoacetophenone, its halo-substituted derivatives, and 1-bromo-1-phenyl-2-propanone gave the corresponding triethylsilyl ethers of enols. In the case of bis(triethylgermyl)mercury, depending on the employed α-bromo ketone, either the enol ether or a mixture of the O- and C-germylation products is formed.

Keywords

Ether Mercury Ketone Enol Enol Ether 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • D. V. Gendin
    • 1
  • O. A. Kruglaya
    • 1
  • I. D. Kalikhman
    • 1
  • N. S. Vyazankin
    • 1
  • G. G. Furin
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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