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N-nitration of salts of primary nitramines by nitryl fluoride

  • R. G. Gafurov
  • B. S. Fedorov
  • L. T. Eremenko
Organic Chemistry
  • 34 Downloads

Conclusions

  1. 1.

    A method has been developed for the N-nitration of the anions of primary nitramines with nitryl fluoride to N,N-dinitramines.

     
  2. 2.

    Bulky tetraalkylammonium cations in nitramine salts direct the attack of nitryl fluoride on the nucleophilic amine center of the ion, whereas the harder metal cations favor O-nitration.

     
  3. 3.

    In the nitration of nitramine anions by nitronium tetrafluoroborate, the opposite effect is observed with respect to the influence of the salt cation on the outcome of the reaction, i.e., bulky, soft cations favor O-nitration.

     

Keywords

Fluoride Opposite Effect Metal Cation Nitration Tetrafluoroborate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • R. G. Gafurov
    • 1
  • B. S. Fedorov
    • 1
  • L. T. Eremenko
    • 1
  1. 1.Department of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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