Conclusions
The influence of the halogen on the strength of the adjacent C-Li bond has been evaluated on the basis of thermodynamic and quantum-chemical calculations, and it has been shown that monomolecular decomposition is preferable for LiCHCl2, LiCCl3, LiCF3, and o-FC6H4Li under the conditions of the experiment, while such decomposition is impossible for LiCH2Cl.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2183–2186, October, 1979.
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Faustov, V.I., D'yachenko, A.I. & Nefedov, O.M. Unstable halogen-containing organolithium compounds. 7. Thermodynamic calculations of the decomposition mechanism of halogen-containing organolithium compounds. Russ Chem Bull 28, 2006–2009 (1979). https://doi.org/10.1007/BF00947541
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DOI: https://doi.org/10.1007/BF00947541