Advertisement

A mass-spectrometric investigation of nitrogen trifluoride by the electron shock method

  • A. V. Dudin
  • A. V. Baluev
  • L. N. Gorokhov
Inorganic Chemistry

Conclusions

  1. 1.

    The authors have investigated electron shock ionization of the NF3 molecule with formation of positive and negative ions. They have measured the appearance potential and the initial kinetic energies of the ions.

     
  2. 2.

    They have calcualted the splitting energies of the bonds D0(FN-F) and D0(N-F) and the lower limit of the electron affinity of the NF2 radical.

     

Keywords

Nitrogen Kinetic Energy Lower Limit Electron Affinity Splitting Energy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. M. Reese and V. H. Dibeler, J. Chem. Phys.,24, 1145 (1956).Google Scholar
  2. 2.
    J. T. Herron and V. H. Dibeler, J. Res. Nat. Bur. Standards,65A, 405 (1961).Google Scholar
  3. 3.
    V. H. Dibeler and J. A. Walker, Inorg. Chem.,8, 1728 (1969).Google Scholar
  4. 4.
    P. J. Bassett and D. R. Lloyd, J. Chem. Soc. Dalton Trans., 248 (1972).Google Scholar
  5. 5.
    J. C. J. Thynne, J. Phys. Chem.,73, 1586 (1969).Google Scholar
  6. 6.
    P. W. Harland and J. L. Franklin, J. Chem. Phys.,61, 1621 (1974).Google Scholar
  7. 7.
    A. V. Dudin, A. V. Baluev, and L. N. Gorokhov, Izv. Akad. Nauk SSSR, Ser. Khim., 1306 (1978).Google Scholar
  8. 8.
    J. W. Warren, Nature,165, 810 (1950).Google Scholar
  9. 9.
    C. E. Berry, Phys. Rev.,78, 597 (1950).Google Scholar
  10. 10.
    A. B. Cornford, D. C. Frost, F. G. Herring, and C. A. McDowell, J. Chem. Phys.,54, 1872 (1950).Google Scholar
  11. 11.
    V. N. Kondrat'ev (editor), Splitting Energies of Chemical Bonds. Ionization Potentials and Electron Affinity. A reference work [in Russian], Nauka (1974).Google Scholar
  12. 12.
    V. P. Glushko (editor), Thermal Constants of Substances. A reference work [in Russian], No. 3, VINITI (1968).Google Scholar
  13. 13.
    JANAF Thermochemical Tables, 2nd edition, U. S. NBS-NSRDS (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • A. V. Dudin
    • 1
    • 2
  • A. V. Baluev
    • 1
    • 2
  • L. N. Gorokhov
    • 1
    • 2
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRChernogolovka
  2. 2.Institute of High TemperaturesAcademy of Sciences of the USSRMoscow

Personalised recommendations