Hexakis(trimethylsilylmethyl)ditungsten as catalyst for metathesis reactions of olefins

  • N. B. Bespalova
  • É. D. Babich
  • V. M. Vdovin
Brief Communications
  • 16 Downloads

Conclusions

W2[CH2Si(CH3)3]6 initiates the polymerization of cyclic olefins, and in combination with WCl6 is active in the metathesis of both linear and cyclic olefins.

Keywords

Polymerization Metathesis Cyclic Olefin Metathesis Reaction Hexakis 

Literature cited

  1. 1.
    R. J. Haines and G. J. Leigh, Chem. Soc. Rev.,14, 155 (1975).Google Scholar
  2. 2.
    B. A. Dolgoplosk, K. L. Makovetskii, and E. I. Tinyakova, Dokl. Akad. Nauk SSSR,202, 871 (1972).Google Scholar
  3. 3.
    W. Mowat, A. Shortland, G. Yagupsky, N. Hill, M. Yagupsky, and J. Wilkinson, J. Chem. Soc. Dalton Trans.,1972, 533.Google Scholar
  4. 4.
    A. A. Vasil'ev, Zh. Obshch. Khim.,17, 923 (1947).Google Scholar
  5. 5.
    C. Tosi, F. Ciampelly, and G. Dall'Asta, J. Polymer Sci.,11, 529 (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • N. B. Bespalova
    • 1
  • É. D. Babich
    • 1
  • V. M. Vdovin
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow

Personalised recommendations