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Intramolecular cyclization of alkoxycarbonylcarbenes during thermal decomposition of alkyl diazoacetates

  • I. E. Dolgii
  • E. A. Shapiro
  • G. V. Lun'kova
  • O. M. Nefedov
Brief Communications

Conclusions

We were the first to observe the intramolecular cyclization of alkoxycarbonylcarbenes under the conditions for the thermal decomposition of alkyl diazoacetates, which proceeds via the insertion of the carbene C atom in theβ-C -H bond of the ester group.

Keywords

Ester Thermal Decomposition Carbene Ester Group Intramolecular Cyclization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • I. E. Dolgii
    • 1
  • E. A. Shapiro
    • 1
  • G. V. Lun'kova
    • 1
  • O. M. Nefedov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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