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Rearrangement in the series of aryl-substituted dihydrothiophenocycloalkanones and the influence of carboxylic acid chlorides on this process

  • Ya. L. Gol'dfarb
  • B. P. Fabrichnyi
  • V. K. Zavyalova
  • V. S. Bogdanov
Organic Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    The primary products of the reaction of thiophenocycloalkanones with benzene or chlorobenzene in the presence of AlCl3 are 3-aryl-substituted 2,3-dihydrothiophenocycloalkanones.

     
  2. 2.

    2- and 3-Substituted compounds of this type isomerize into one another by the action of AlCl3.

     

Keywords

Chloride Benzene Carboxylic Acid AlCl3 Chlorobenzene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
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    V. P. Litvinov and Ya. L. Gol'dfarb, Adv. Heterocycl. Chem.,19, 193 (1976).Google Scholar
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    G. A. Olah and S. J. Kuhn, J. Am. Chem. Soc.,80, 6541 (1958).Google Scholar
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    D. J. Cram, J. Am. Chem. Soc.,74, 2129 (1952); V. A. Koptyug, Isomerization of Aromatic Compounds [in Russian], Izd. Sib. Otd. Akad. Nauk SSSR, Novosibirsk (1963).Google Scholar
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    C. R. Noller and R. Adams, J. Am. Chem. Soc.,46, 1889 (1924).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • Ya. L. Gol'dfarb
    • 1
  • B. P. Fabrichnyi
    • 1
  • V. K. Zavyalova
    • 1
  • V. S. Bogdanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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