Reaction of phosphorus pentoxide with α,α,ω-trihydroperfluoroalkanols

  • A. V. Fokin
  • V. A. Komarov
  • A. F. Kolomiets
  • A. I. Rapkin
  • K. I. Pasevina
  • T. M. Potarina
  • O. V. Verenikin
Organic Chemistry
  • 27 Downloads

Conclusions

  1. 1.

    We have examined the reactions in P2O5-α,α,ω-trihydroperfluoroalkanol systems and found the conditions for simple conversions to tris(α,α,ω-trihydroperfluoroalkyl) phosphates. We suggest a mechanism for their formation.

     
  2. 2.
    Tris(α,α,ω-trihydroperfluoroalkyl) phosphates react with P2O5 at high temperature to form compounds of the type
    the fluorinating ability diminishes rapidly with increasing separation of the cohydrogen from the ether bond.
     
  3. 3.

    2,2,-Difluoro-2-nitroethanol and P2O5 form bis(2,2-difluoro-2-nitroethyloxy)methane.

     

Keywords

Phosphate Methane Phosphorus P2O5 Phosphorus Pentoxide 

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. V. Fokin
  • V. A. Komarov
  • A. F. Kolomiets
  • A. I. Rapkin
  • K. I. Pasevina
  • T. M. Potarina
  • O. V. Verenikin

There are no affiliations available

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