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The kinetics of the dimerization of 2-[4′-dialkyl(aryl)aminophenyl]-1,3-indandionyl radicals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Kinetic and thermodynamic parameters have been determined for the 2Φ. ⇌ Φ-Φ system, Φ. being a 2-(4′-dialkylaminophenyl)-1,3-indandionyl radical.

  2. 2.

    Recombination of Φ. radicals is a diffusion-limited process.

  3. 3.

    The Φ-Φ dimers are thermochromic and photochromic compounds.

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Literature cited

  1. V. V. Moiseev and I. T. Poluéktov, Usp. Khim.,42, 471 (1973).

    Google Scholar 

  2. A. B. Gagarina, L. M. Pisarenko, and N. M. Émanuél, Dokl. Akad. Nauk SSSR,212, 653 (1973).

    Google Scholar 

  3. A. B. Gagarina, L. M. Pisarenko, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,221, 640 (1975).

    Google Scholar 

  4. V. A. Kuz'min, I. V. Khudyakov, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,206, 1154 (1972).

    Google Scholar 

  5. I. T. Poluéktov, V. V. Moiseev, I. F. Gainulin, and A. I. Yasmenko, Zh. Org. Khim.,11, 1300 (1975).

    Google Scholar 

  6. I. V. Khudyakov, L. M. Pisarenko, A. B. Gagarina, V. A. Kuz'min, and N. M. Émanuél', Dokl. Akad. Nauk SSSR,222, 1390 (1975).

    Google Scholar 

  7. N. M. Émanuél' and V. G. Knorre, Course in Chemical Kinetics [in Russian], Vysshaya Shkola (1974), Chap. IV.

  8. R. Prechel and R. W. Selwood, J. Am. Chem. Soc.,63, 3397 (1941).

    Google Scholar 

  9. V. A. Kuz'min (Kuzmin), I. V. Khudyakov (Khudjakov), P. P. Levin, A. S. Tatikolov, and N. M. Émanuél' (Emanuel), Proceedings of the Second Conference on the Degradation and Stabilization of Polymers, Arnhem (1976), p. 123.

  10. Handbook of Chemistry and Physics, McGraw-Hill, New York (1967).

  11. I. V. Khudyakov and V. A. Kuz'min, Usp. Khim.,44, 1748 (1975).

    Google Scholar 

  12. S. W. Benson, Thermochemical Kinetics, Wiley-Interscience (1968).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1499–1502, July, 1978.

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Khudyakov, I.V., Yasmenko, A.I., Khardin, A.P. et al. The kinetics of the dimerization of 2-[4′-dialkyl(aryl)aminophenyl]-1,3-indandionyl radicals. Russ Chem Bull 27, 1310–1313 (1978). https://doi.org/10.1007/BF00946860

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  • DOI: https://doi.org/10.1007/BF00946860

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