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Cryoscopic and11B NMR spectroscopic study of bromine-containing (dialkylamino)- and (diphenylamino) boranes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was shown by the cryoscopy method that in benzene solution, in the concentration range 0.03–0.1 mole/liter, the dibromo(dialkylamino)boranes exist predominantly as the monomers.

  2. 2.

    The values of the11B NMR chemical shifts of the studied dibromo(dialkylamino)- and dibromo(diphenylamlno)boranes testify to their existence in the monomeric form also in the absence of a solvent, i.e., in either the liquid or molten state.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    E. A. Balabanova, T. G. Sevast'yanova, V. S. Bogdanov, J. D. Colley & V. I. Spitsyn

Authors
  1. E. A. Balabanova
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  2. T. G. Sevast'yanova
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  3. V. S. Bogdanov
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  4. J. D. Colley
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  5. V. I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2638–2639, November, 1978.

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Balabanova, E.A., Sevast'yanova, T.G., Bogdanov, V.S. et al. Cryoscopic and11B NMR spectroscopic study of bromine-containing (dialkylamino)- and (diphenylamino) boranes. Russ Chem Bull 27, 2360–2362 (1978). https://doi.org/10.1007/BF00946700

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  • DOI: https://doi.org/10.1007/BF00946700

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