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Ionic hydrogenation of carboxylic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1

    The unsymmetrical anhydrides of carboxylic acids are capable of being reduced by the CF3COOH-R3SiH system.

  2. 2.

    An ionic mechanism was proposed for the reduction, which includes the intermediate formation of the acyl cation.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    D. N. Kursanov, Z. N. Parnes, G. D. Kolomnikova & M. I. Kalinkin

Authors
  1. D. N. Kursanov
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  2. Z. N. Parnes
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  3. G. D. Kolomnikova
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  4. M. I. Kalinkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2413–2416, October, 1978.

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Kursanov, D.N., Parnes, Z.N., Kolomnikova, G.D. et al. Ionic hydrogenation of carboxylic acids. Russ Chem Bull 27, 2147–2149 (1978). https://doi.org/10.1007/BF00946550

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  • DOI: https://doi.org/10.1007/BF00946550

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