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Reaction of π-cyclopentadienyl complexes of manganese and rhenium with mercuric chloride

  • A. G. Ginzburg
  • G. K. I. Magomedov
  • A. S. Frenkel'
  • V. N. Setkina
  • D. N. Kursanov
Brief Communications

Conclusions

  1. 1.

    The C5H5M(CO)2L complexes when reacted with HgCl2 in CH2Cl2, CHCl3 or C6H6 form adducts of composition C5H5M(CO)2L ·nHgCl2, whereone of the HgCl2 molecules is attached to either the central Mn or Re atom.

     
  2. 2.

    The formation of the adducts leads to an increase in the frequencies and a change in the intensities of the bands of the asymmetric and symmetric νco vibrations.

     

Keywords

Chloride Manganese Adduct CH2Cl2 C6H6 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. G. Ginzburg
    • 1
  • G. K. I. Magomedov
    • 1
  • A. S. Frenkel'
    • 1
  • V. N. Setkina
    • 1
  • D. N. Kursanov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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