Transformations of α-4,5-epoxycarane under influence of HCl

  • G. Sh. Bikbulatova
Brief Communications

Conclusions

The reaction of α-4,5-epoxycarane with HCl proceeds with the preferential opening of the oxide ring at the C5 atom and the formation of m-menthene derivatives.

Keywords

Oxide Preferential Opening Oxide Ring 

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Literature cited

  1. 1.
    B. A. Arbuzov, Z. G. Isaeva, G. Sh. Bikbulatova, and N. I. Semakhina, Dokl. Akad. Nauk SSSR,207, 853 (1972).Google Scholar
  2. 2.
    W. Cocker and D. Grayson, J. Chem. Soc., Perkin Trans.,1, 1975, 1217.Google Scholar
  3. 3.
    G. Ohloff and W. Giersch, Helv. Chim. Acta,51, 1328 (1968).Google Scholar
  4. 4.
    J. Wolinsky, J. Hamsher, and R. Hutchins, J. Org. Chem.,35, 207 (1970).Google Scholar
  5. 5.
    W. Cocker, P. V. R. Shannon, and P. A. Staniland, J. Chem. Soc.,C1967, 485.Google Scholar
  6. 6.
    G. P. Payne, Tetrahedron,18, 763 (1962).Google Scholar
  7. 7.
    K. Gollnick and G. Schade, Ann. Chem.,721, 133 (1969).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • G. Sh. Bikbulatova
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR

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