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Reactions of cycloalkyl platinum-mercury compounds: Fragmentation under the action of trityl fluoborate and exchange of ligands on the platinum atom

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The fragmentation of cycloalkyl platinum-mercury compounds under the action of Ph3C+− BF 4 has been studied.

  2. 2.

    The replacement of triphenylphosphine by a bidentate ligand in the coordination sphere of the platinum with maintenance of the Pt-Hg σ bond has been carried out.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2372–2375, October, 1978.

We thank G. M. Mikheeva for determining the elemental composition of the compounds investigated.

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Bashilov, V.V., Suleimanov, G.Z., Sokolov, V.I. et al. Reactions of cycloalkyl platinum-mercury compounds: Fragmentation under the action of trityl fluoborate and exchange of ligands on the platinum atom. Russ Chem Bull 27, 2105–2108 (1978). https://doi.org/10.1007/BF00946536

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  • DOI: https://doi.org/10.1007/BF00946536

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