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Synthesis of methacrylate and thiomethacrylate derivatives of tetra-and pentamethyl-2,4,6,8-tetrathiaadamantane and their copolymerization with methyl methacrylate

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have synthesized monomers, thiaadamantane derivatives of methacrylic acid, and examined their copolymerization with methyl methacrylate and the properties of the copolymers.

  2. 2.

    Thiaadamantyl methacrylates are not susceptible to radical polymerization but copolymerize to form thermally stable copolymers.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2339–2343, October, 1978.

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Tolstikov, G.A., Lerman, B.M., Galin, F.Z. et al. Synthesis of methacrylate and thiomethacrylate derivatives of tetra-and pentamethyl-2,4,6,8-tetrathiaadamantane and their copolymerization with methyl methacrylate. Russ Chem Bull 27, 2072–2075 (1978). https://doi.org/10.1007/BF00946530

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  • DOI: https://doi.org/10.1007/BF00946530

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