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Hydrogenation of aromatic nitro compounds in the presence of an iridium catalyst

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The hydrogenation of aromatic nitro compounds on an iridium catalyst proceeds rapidly with quantitative yields of the amino products; the catalyst is highly stable in operation.

  2. 2.

    In the hydrogenation of halogen-containing nitro compounds the ratio of the apparent rate constants for hydrogenation and dehalogenation of the nitro compound is much higher than on catalysts examined earlier.

  3. 3.

    The iridium catalyst is potentially useful in the production of halogen-substituted amines by hydrogenation of halonitrobenzenes.

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Literature cited

  1. Catalytic Liquid-Phase Reduction of Aromatic Nitro Compounds [in Russian], Khimiya, Leningrad (1969), p. 5.

  2. É. N. Bakhanova, A. S. Astakhova, Kh. A. Brikenshtein, V. G. Dorokhov, V. I. Savchenko, M. L. Khidekel', and I. S. Monakhova, Inventor's Certificate No. 287005; Byull. Izobr., No. 35 (1970); Izv. Akad. Nauk SSSR, Ser. Khim.,1970, 499;1972, 1993.

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. I. Savchenko, V. G. Dorokhov, R. S. Tsareva, G. M. Baimashova, N. A. Chekh, É. N. Izakovich, Kh. A. Brikenshtein & M. L. Khidekel'

Authors
  1. V. I. Savchenko
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  2. V. G. Dorokhov
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  3. R. S. Tsareva
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  4. G. M. Baimashova
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  5. N. A. Chekh
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  6. É. N. Izakovich
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  7. Kh. A. Brikenshtein
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  8. M. L. Khidekel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2329–2332, October, 1978.

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Savchenko, V.I., Dorokhov, V.G., Tsareva, R.S. et al. Hydrogenation of aromatic nitro compounds in the presence of an iridium catalyst. Russ Chem Bull 27, 2062–2065 (1978). https://doi.org/10.1007/BF00946527

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  • DOI: https://doi.org/10.1007/BF00946527

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