Conclusions
-
1.
Study has been made of the interaction of chromium and iron vapors with toluene, mesitylene, and durol on liquid-nitrogen cooled surfaces. IR spectroscopy has been used to confirm the low-temperature formation of previously unknown bisarene iron (0) complexes. Decomposition temperatures have been determined for these compounds.
-
2.
The fact that the skeletal vibration frequencies of the various bisarene chromium complexes were essentially identical suggests that the strength of the metal-ligand bond increases as more and more methyl substituents are introduced into the benzene ring.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
K. I. Klabunde and I. Y. F. Low, J. Organomet. Chem.,51, 33 (1973).
E. A. Koerner von Gustorf, O. Jaenicke, and O. E. Polansky, Angew. Chem. Int. Ed.,11, 532 (1972).
P. L. Timms, Angew. Chem. Int. Ed.,14, 273 (1975).
V. T. Aleksanyan and T. S. Kurtikyan, Zh. Koord. Khim.,3, 1548 (1977).
E. O. Fischer and F. Rohrscheid, Z. Naturforsch.,17b, 483 (1962).
S. S. Lin and A. Kant, J. Phys. Chem.,73, 2450 (1969).
A. Kant and B. Strauss, J. Chem. Phys.,45, 3161 (1966).
A. M. Yampol'skii and V. A. Il'in, Galvanotechnical Handbook [in Russian], Mashinostroenie, Leningrad (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2298–2301, October, 1978.
Rights and permissions
About this article
Cite this article
Kurtikyan, T.S., Aleksanyan, V.T. Study of the low-temperature interaction of iron vapors with methyl derivatives of benzene by IR spectroscopy. Russ Chem Bull 27, 2034–2036 (1978). https://doi.org/10.1007/BF00946521
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00946521