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Stabilization of free radicals through γ irradiation of molecules adsorbed by zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the stability and ESR spectra of free radicals resulting from γ irradiation at −196°C of triethylbenzene, the diethyl ester of dimethylmalonic acid, and tert-butylbenzene adsorbed on NaX and CaX zeolites at room temperature and above. Only the radicals formed from irradiation of molecules with diameters commensurate with the zeolite aperture diameters show anomalously high stability.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    N. T. Kartel', N. N. Tsyba, V. V. Strelko, K. M. Nikolaev, N. S. Polyakov & M. M. Dubinin

  2. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    N. T. Kartel', N. N. Tsyba, V. V. Strelko, K. M. Nikolaev, N. S. Polyakov & M. M. Dubinin

Authors
  1. N. T. Kartel'
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  2. N. N. Tsyba
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  3. V. V. Strelko
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  4. K. M. Nikolaev
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  5. N. S. Polyakov
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  6. M. M. Dubinin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2243–2249, October, 1978.

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Kartel', N.T., Tsyba, N.N., Strelko, V.V. et al. Stabilization of free radicals through γ irradiation of molecules adsorbed by zeolites. Russ Chem Bull 27, 1982–1987 (1978). https://doi.org/10.1007/BF00946510

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  • DOI: https://doi.org/10.1007/BF00946510

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