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Thermal desorption in catalytic systems 13. The surface adsorption of H2O, CO, and CO2 on copper oxide-zinc-aluminum-calcium catalysts for low-temperature conversion of carbon monoxide

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The relation between the thermodesorption parameters for Co, CO2, and H2O and the activity of copper oxide-zinc-aluminum-calcium catalysts has been discussed. It is suggested that high catalytic activity is associated with high CO, and low CO2 and H2O, adsorption on the nonuniform surface. The thermodesorption parameters are determined by the oxidation-reduction treatment to which the catalyst has been subjected.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. D. Nissenbaum, V. V. Rozanov, V. N. Gel'man, E. Z. Golosman, A. M. Rubinshtein, S. V. Krashennikov & V. I. Yakerson

  2. Novomoskovsk Branch of the State Institute for the Nitrogen Industry, USSR

    V. D. Nissenbaum, V. V. Rozanov, V. N. Gel'man, E. Z. Golosman, A. M. Rubinshtein, S. V. Krashennikov & V. I. Yakerson

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  1. V. D. Nissenbaum
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  2. V. V. Rozanov
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  3. V. N. Gel'man
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  4. E. Z. Golosman
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  5. A. M. Rubinshtein
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  6. S. V. Krashennikov
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  7. V. I. Yakerson
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2233–2238, October, 1978.

For Communication 12, cf. [1].

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Nissenbaum, V.D., Rozanov, V.V., Gel'man, V.N. et al. Thermal desorption in catalytic systems 13. The surface adsorption of H2O, CO, and CO2 on copper oxide-zinc-aluminum-calcium catalysts for low-temperature conversion of carbon monoxide. Russ Chem Bull 27, 1972–1977 (1978). https://doi.org/10.1007/BF00946508

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  • DOI: https://doi.org/10.1007/BF00946508

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