Conclusions
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1.
The authors have recorded the IR and Raman spectra of heteropolytungstates with the general formula XW10O36 n− and have made an empirical attribution of the observed bands.
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2.
In the aqueous solutions, the structure of the HPA corresponds to the structures found by diffraction methods for the crystalline state.
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Literature cited
H. T. Evans, Perspect. Struct. Chem.,4, 3 (1974).
L. P. Kazanskii, E. A. Torchenkova, and V. I. Spitsyn, Usp. Khim.,43, 1337 (1974).
M. T. Pope, Inorg. Chem.,11, 1973 (1972).
L. P. Kazanskii, E. A. Torchenkova, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,209, 141 (1973).
L. P. Kazanskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 502.
C. Roccioccioli-Deltcheff, R. Thouvenot, and R. Frank, Spectrochim. Acta,32A, 587 (1976).
R. D. Peacock and T. J. R. Weakley, J. Chem. Soc.,A 1971, 1836 (1937).
J. Iball, J. N. Low, and T. J. R. Weakley, J. Chem. Soc., Dalton Trans.,1974, 2021.
A. M. Golubev, L. P. Kazanskii, E. A. Torchenkova, V. I. Simonov, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,221, 351 (1975).
R. Mattes, H. Bierbusse, and J. Fuchs, Z. Anorg. Allg. Chem.,385, 230 (1971).
J. Fuchs, H. Hartle, W. Schiller, and G. Gerlach, Acta Crystallogr.,B32, 740 (1976).
V. Cordis, K. N. Tytko, and O. Glemser, Z. Naturforsch.,30b, 834 (1975).
M. A. Fedotov, A. M. Golubev, and L. P. Kazanskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 2840.
F. A. Cotton and R. M. Wing, Inorg. Chem.,4, 867 (1965).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2215–2219, October, 1978.
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Kazanskii, L.P., Golubev, A.M., Baburina, I.I. et al. Vibration spectra of XW10O n−36 heteropolyanions. Russ Chem Bull 27, 1956–1960 (1978). https://doi.org/10.1007/BF00946505
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DOI: https://doi.org/10.1007/BF00946505