Chemistry of Heterocyclic Compounds

, Volume 10, Issue 4, pp 460–462 | Cite as

Investigation of lactams

XXII. Protonation and hydrolysis ofα-enamines of capro- and valerolactams
  • V. G. Smirnova
  • A. B. Grigor'ev
  • M. K. Polievktov
  • V. G. Granik
  • N. P. Kostyuchenko
  • I. V. Persianova
  • R. G. Glushkov
Article
  • 21 Downloads

Abstract

From an examination of the PMR spectra, polarographic data, and molecular models ofα-enamines of capro- and valerolactams, it is concluded that there is a different degree of conjugation of the p electrons of the piperidine nitrogen with the enamine double bond and that this explains the differences in the tendency of these compounds to undergo hydrolysis.

Keywords

Nitrogen Hydrolysis Organic Chemistry Double Bond Molecular Model 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • V. G. Smirnova
    • 1
  • A. B. Grigor'ev
    • 1
  • M. K. Polievktov
    • 1
  • V. G. Granik
    • 1
  • N. P. Kostyuchenko
    • 1
  • I. V. Persianova
    • 1
  • R. G. Glushkov
    • 1
  1. 1.S. Ordzhonikidze All-Union Scientific-Research Pharmaceutical-Chemistry InstituteMoscow

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