Abstract
The rate of hydrogenation of the vinyl group ofα-,Β, andγ-vinylpyridines decreases as its distance from the nitrogen atom increases in the presence of the palladium chlorodimethylsulfoxide complex. In binary mixtures of these vinylpyridines, theγ isomer is reduced before the other two isomers.
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N. M. Nazarova, L. Kh. Freidlin, and I. G. Rozhdestvenskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1732 (1967).
L. Kh. Freidlin, N. M. Nazarova, and I. G. Rozhdestvenskaya, Dokl. Akad. Nauk SSSR,176, 1323 (1967).
L. Kh. Freidlin, N. M. Nazarova, and Yu. A. Kopyttsev, Izv. Akad. Nauk SSSR, Ser. Khim., 201 (1972).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 525–526, April, 1974.
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Nazarova, N.M., Freidlin, L.K. & Kopyttsev, Y.A. Hydrogenation of vinylpyridines and styrene in the presence of the palladium chlorodimethylsulfoxide complex. Chem Heterocycl Compd 10, 455–456 (1974). https://doi.org/10.1007/BF00945639
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DOI: https://doi.org/10.1007/BF00945639