Chemistry of Heterocyclic Compounds

, Volume 12, Issue 10, pp 1091–1093 | Cite as

Effect of the nature of the halogen atom on the structure and reactivity of 5-halo-2-nitrofurans

  • V. N. Novikov
  • S. V. Borodaev


5-Chloro-2-nitrofuran was obtained for the first time. A comparative study of the properties (UV, IR, and NMR spectra) of 5-X-2-nitrofurans (X=Cl, Br, I) was made, and the kinetics of their reaction with diethylamine in dioxane were studied. The ratio of the rate constants in the indicated order is 29∶23∶1.


Organic Chemistry Dioxane Halogen Halogen Atom Diethylamine 
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • V. N. Novikov
    • 1
  • S. V. Borodaev
    • 1
  1. 1.Rostov State UniversityRostov-on-Don

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