Theoretical and Experimental Chemistry

, Volume 1, Issue 2, pp 130–133 | Cite as

Frequencies of vapor molecules used to determine the thermal capacity and entropy of alkali-halide crystals

  • G. A. Krestov
  • V. A. Lapin


This method is based on the relation between the frequencies of the molecules in the vapor and in the crystal; it has been used to find the specific heats in the range 0–300δK. The trends are discussed.


Entropy Thermal Capacity Vapor Molecule 
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  1. 1.
    M. Born and Karman, Phys. Zs., 13, 297, 1912.Google Scholar
  2. 2.
    K. F. Herzfeld, Theory of Solids [Russian translation], p. 63, ONTI, Moscow-Leningrad, 1936.Google Scholar
  3. 3.
    A. A. Vorob'ev, Physical Properties of Crystalline Ionic Insulators [in Russian], part 1, p. 119, Izd. Tomsk. Univ., 1960.Google Scholar
  4. 4.
    R. B. Barnes, Zs. phys., 75, 723, 1932.Google Scholar
  5. 5.
    S. Bhagavantam and T. Venkatarayudu, Group Theory and its Application to Physical Problems [Russian translation], IL, Moscow, 1959.Google Scholar
  6. 6.
    W. Klemperer, W. G. Norris, A. Büchler and Emslie, J. Chem. Phys., 33, 1534, 1960.Google Scholar
  7. 7.
    L. Wharton, W. Klemperer, L. P. Gold, R. Strauch, J. J. Gallagher, and V. E. Derr, J. Chem. Phys., 38, 1203, 1963.Google Scholar
  8. 8.
    S. A. Rise and W. Klemperer, J. Chem. Phys., 27, 573, 1957.Google Scholar
  9. 9.
    K. S. Krasnov and A. I. Maksimov, Optika i Spektroskopiya, 8, 403, 1960.Google Scholar
  10. 10.
    K. Clusius, J. Goldmann and A. Perlick, Z. Naturforch., 4a, 424, 1949.Google Scholar
  11. 11.
    W. T. Berg and J. A. Morrison, Proc. Roy. Soc., London, A242, 467, 478, 1957.Google Scholar
  12. 12.
    E. F. Westrum, Jr. and K. S. Pitzer, J. Am. Chem. Soc., 71, 1946, 1949.Google Scholar
  13. 13.
    A. M. Karo, J. Chem. Phys., 31, 1489, 1959.Google Scholar
  14. 14.
    A. M. Karo, J. Chem. Phys., 33, 7, 1960.Google Scholar
  15. 15.
    N. N. Feodos'ev, Zh. Fiz. Khim., 12, 291, 1938.Google Scholar
  16. 16.
    P. G. Strelkov, E. S. Itskevich, V. N. Kostryukov, and G. G. Mirskaya, Zh. Fiz. Khim., 28, 645, 1954.Google Scholar
  17. 17.
    G. A. Krestov, Izv. VUZ. Khimiya i Khim. Tekhnol., 6, 4, 578, 1963.Google Scholar
  18. 18.
    K. B. Yatsimirskii and G. A. Krestov, Zh. Fiz. Khim., 34, 10, 2263, 1960.Google Scholar

Copyright information

© The Faraday Press, Inc. 1966

Authors and Affiliations

  • G. A. Krestov
    • 1
  • V. A. Lapin
    • 1
  1. 1.Ivanovo Institute of Chemical TechnologyRussia

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