Skip to main content
SpringerLink
Log in

Effects of the local magnetic fields of paramagnetic particles on chemical reactions

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

Effects on reactivity from local magnetic fields are considered for conjugated monomers and polymers containing paramagnetic centers. The local activation effect is discussed in phenomenological terms in relation to complexes formed with diamagnetic reagents; results are given for the low-temperature pyrolysis of anthracene, the thermal polymerization of pyridine and quinoline on zinc chloride, interactions with conjugated free-radical systems (including diphenylpicrylhydrazyl DPPH), inhibition of thermal oxidation, and thermal polymerization of tetracyanoethylene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. W. Selwood, Magnetochemistry, 1956.

  2. H. Smid et al., Zeits. Elektrochemie, 51, 37, 1945; J. Leffler and M. Sienko, J. Chem. Phys., 17, 215, 1949; First Biomagnetic Symposium, Nature. 193, 215, 1962; J. Mulay, Nature, 190, 1019, 1961.

    Google Scholar 

  3. D. F. Evans, Nature, 173, 534, 1954; A. Munck and J. Scott, Nature, 177, 587, 1956.

    Google Scholar 

  4. P. Yuster and S. Wiesmann, J. Chem. Phys., 17, no. 12, 1182, 1949.

    Google Scholar 

  5. A. N. Terenin, The Photochemistry of Dyes [in Russian], Moscow, 1947.

  6. A. Farkas and H. Sachsse, Z. Phys. Chem., B 23, 1, 19, 1933.

    Google Scholar 

  7. G. M. Schwab and V. Agliardi, Ber., 73, 95, 1940.

    Google Scholar 

  8. R. Harman and H. Eyring, J. Chem. Phys., 10, 557, 1942.

    Google Scholar 

  9. E. Gellers and K. Pitzer, J. Amer. Chem. Soc., 77, 1957, 1955.

    Google Scholar 

  10. M. Levy and M. Szwarc, J. Chem. Phys., 22, 1621, 1954.

    Google Scholar 

  11. J. Smid and M. Szwarc, J. Amer. Chem. Soc., 78, 3322, 1956.

    Google Scholar 

  12. M. Szwarc, J. Chem. Phys., 23, no. 1, 204, 1955.

    Google Scholar 

  13. A. A. Berlin, L. A. Blyumenfel'd, M. I. Cherkashin, A. E. Kalmanson, and O. G. Sel'skaya, Vysokomolek. soed., 1, no. 9, 1361, 1961.

    Google Scholar 

  14. A. A. Berlin, Khim. Prom., no. 12, 23, 1962.

    Google Scholar 

  15. L. A. Blyumenfel'd and V. A. Benderskii, Zh. Strukt. Khim., 4, 405, 1963.

    Google Scholar 

  16. A. A. Berlin and L. A. Blyumenfel'd, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 9, 1720, 1964.

    Google Scholar 

  17. A. A. Berlin, V. A. Vonsyatskii, and L. A. Lyubchenko, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 7, 1312, 1962.

    Google Scholar 

  18. A. A. Berlin and S. I. Bass, Dokl. Akad. Nauk SSSR, 150, 4, 795, 1963.

    Google Scholar 

  19. A. A. Berlin, V. A. Grigorovskaya, V. P. Parini, and Kh. Gafurov, Dokl. Akad. Nauk SSSR, 156, no. 6, 1371, 1964.

    Google Scholar 

  20. V. P. Kovaleva, D. A. Topchiev, V. A. Kabanov, and V. A. Kargin, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 2, 387, 1963.

    Google Scholar 

  21. D. A. Topchiev, V. G. Popov, V. A. Kabanov, and V. A. Kargin, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 2, 391, 1964.

    Google Scholar 

  22. A. A. Berlin and V. A. Vonsyatskii, Dokl. Akad. Nauk SSSR, 154, no. 3, 627, 1964.

    Google Scholar 

  23. V. A. Vonsyatskii, G. I. Kalyaev, and A. A. Berlin, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 2, 304, 1964.

    Google Scholar 

  24. A. A. Berlin and V. A. Vonsyatskii, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 7, 1313, 1962.

    Google Scholar 

  25. A. A. Berlin et al., Dokl. Akad. Nauk SSSR, 144, no. 6, 1316, 1962.

    Google Scholar 

  26. A. A. Berlin, B. I. Liogon'kii, and V. P. Parini, Vysokomolek. soed., 2, 689, 1960.

    Google Scholar 

  27. A. A. Berlin and V. A. Grigorovskaya, Izv. Akad. Nauk SSSR, Otdel, Khim. Nauk, no. 8, 1492, 1962.

    Google Scholar 

  28. A. A. Berlin and V. A. Grigorovskaya, Izv. Akad. Nauk SSSR. Otdel. Khim. Nauk, no. 9, 1652, 1963.

    Google Scholar 

  29. T. L. Jacobs and W. P. Tuttle, J. Amer. Chem. Soc., 71, 1313, 1949.

    Google Scholar 

  30. A. A. Berlin and V. A. Grigorovskaya, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 10, 1854, 1963.

    Google Scholar 

  31. N. M. Lapshin, N. I. Ovcharenko, and M. L. Khidikel, Zh. Strukt. Khim., 5, no. 2, 305, 1964.

    Google Scholar 

  32. A. A. Berlin, V. P. Parini, E. L. Frankevich, and L. G. Cherkashina, Izv. Akad. Nauk SSSR, Otdel, Khim. Nauk, no. 11, 2109, 1964.

    Google Scholar 

  33. A. A. Berlin and A. G. Matveeva, Dokl. Akad. Nauk SSSR, 1965.

  34. V. A. Grigorovskaya and A. A. Berlin, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 10, 1913, 1964.

    Google Scholar 

  35. J. Czecalla, Z. Electrochem., 66, no. 1, 65, 1962.

    Google Scholar 

  36. A. A. Berlin et al., Vysokomol. Soed., no. 10, 1964.

  37. A. A. Berlin, L. A. Blyumenfel'd, and N. N. Semenov, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, no. 9, 1689, 1959.

    Google Scholar 

  38. A. V. Topchiev, M. A. Geiderikh, B. E. Davydor, V. A. Kargin, B. A. Krentsel, I. M. Kustanovich, and L. S. Polak, Dokl. Akad. Nauk SSSR, 128, 312, 1959.

    Google Scholar 

  39. E. S. Dokukina, S. Z. Roginskii, M. M. Sakharov, A. V. Topchiev, M. A. Geiderikh, B. E. Davydor, and B. A. Krentsel, Dokl. Akad. Nauk SSSR, 137, 893, 1961.

    Google Scholar 

  40. A. N. Mesmeyanov, A. M. Rubinshtein, A. A. Dulov, A. A. Slinkin, M. I. Rybinskaya, and G. A. Slonimskii, Dokl. Akad. Nauk SSSR, 135, 609, 1960.

    Google Scholar 

  41. S. Z. Roginskii, A. A. Berlin, et al., Dokl. Akad. Nauk SSSR, 148, no. 1, 118, 1963.

    Google Scholar 

  42. G. Gallard, T. Laederich, R. Salle, Bull. Soc. Chim. France, no. 10, 2204, 1963.

    Google Scholar 

  43. US Patent No. 3075950, 29 January 1963.

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, AS USSR Lomonosov Institute of Fine-Chemical Technology, Moscow

    A. A. Berlin & S. I. Bass

Authors
  1. A. A. Berlin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. I. Bass
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berlin, A.A., Bass, S.I. Effects of the local magnetic fields of paramagnetic particles on chemical reactions. Theor Exp Chem 1, 95–99 (1965). https://doi.org/10.1007/BF00945566

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00945566

Keywords

Search

Navigation