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Theoretical and Experimental Chemistry

, Volume 21, Issue 2, pp 168–174 | Cite as

Reaction kinetics in replacement of zinc ions by copper ions in complexes with cyclic and noncyclic tetramines

  • K. B. Yatsimirskii
  • V. V. Pavlishchuk
  • E. V. Rybak-Akimova
Article

Abstract

A kinetic study has been made of reactions of zinc ion replacement by copper in complexes with macrocyclic and noncyclic tetramines. The activation parameters of these processes have been determined, and reaction mechanisms are proposed. A kinetic macrocyclic effect has been found in reactions of central atom replacement in tetraazamacrocyclic complexes of zinc.

Keywords

Copper Zinc Reaction Mechanism Kinetic Study Reaction Kinetic 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • K. B. Yatsimirskii
    • 1
  • V. V. Pavlishchuk
    • 1
  • E. V. Rybak-Akimova
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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