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Intercalation and photolysis of PbI2 crystals

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Abstract

It has been established that reductants sensitize the photolysis of PbI2 but only commencing from a threshold concentration. An anisotropy is observed in the photodecomposition of single crystals in the presence of amines. It has been shown that intercalation competes with the sensitization of photolysis. An interpretation of the effect is proposed.

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Literature cited

  1. V. M. Koshkin, “Intercalation compounds of semiconductors and dielectrics,” Izv. Akad. Nauk Latv. SSR, Ser. Fiz. Tekh. Nauk, No. 6, 90–98 (1981).

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  2. M. R. Tubbs, “The optical properties and chemical decomposition of halides with layer structures. 2,” Phys. Status Solidi,67, No. 1, 11–51 (1975).

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  3. N. Pangelova, M. Pancheva, and A. Katsev, “Light-sensitive lead iodide suspensions,” J. Signalauf-zeichnungsmateriale,7, No. 4, 282–284 (1979).

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Authors and Affiliations

  1. Kharkov Polytechnic Institute, USSR

    G. I. Gurina, V. D. Evtushenko, A. Yu. Kobyakov & V. M. Koshkin

Authors
  1. G. I. Gurina
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  2. V. D. Evtushenko
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  3. A. Yu. Kobyakov
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  4. V. M. Koshkin
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Additional information

Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 21, No. 6, pp. 757–759, November–December, 1985.

We thank L. A. Ageev, A. M. Gorbenko, V. S. Paivin, and K. V. Savchenko for assistance in the experiments.

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Gurina, G.I., Evtushenko, V.D., Kobyakov, A.Y. et al. Intercalation and photolysis of PbI2 crystals. Theor Exp Chem 21, 718–719 (1985). https://doi.org/10.1007/BF00945156

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  • DOI: https://doi.org/10.1007/BF00945156

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