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Reaction ofβ,β -dimethyldivinyl ketone with 2,5-dimethyl- and 1,2,5-trimethyl-4-piperidones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1-(3-Oxo-5-methyl-4-hexen-1-yl)-2,5-dimethyl-4-piperidone, 5-(3-oxo-5-methyl-4-hexen-1-yl)-2, 5-dimethyl-4-piperidone, and 5-(3-oxo-5-methyl-4-hexen-1-yl)-1,2,5-trimethyl-4-piperidone were synthesized. In the absence of a catalystβ,β-dimethyldivinyl ketone adds to 2,5-dimethyl-4-piperidone at the 1-position, while in the presence of alkali it adds at the 5-position.

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Literature cited

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 350–351, March, 1971.

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Tokmurzin, K.K., Sharifkanov, A.S. & Bakhmanov, B. Reaction ofβ,β -dimethyldivinyl ketone with 2,5-dimethyl- and 1,2,5-trimethyl-4-piperidones. Chem Heterocycl Compd 7, 324–325 (1971). https://doi.org/10.1007/BF00944413

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  • DOI: https://doi.org/10.1007/BF00944413

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