Chemistry of Heterocyclic Compounds

, Volume 3, Issue 1, pp 99–100 | Cite as

Dehydrocondensation of triorganosilanes with piperazine and some aliphatic amines in the presence of potassium metal

  • N. S. Nametkin
  • E. S. Vasil'eva
  • V. N. Perchenko


Reaction of CH3(C6H5)2SiH with C4H9NH2 in the presence of potassium metal gives, instead of the expected CH3(C6H5)2SiNHC4H9, benzene, diphenyl, and what is apparently a hitherto unknown substituted cyclodisolazane
. The Si-C6H5 bond is broken not only by alkali metals, but also by their amides. For the case of piperazine it is shown that heterocyclic diamines react considerably more readily with trialkylsilanes than do aliphatic secondary amines.


Potassium Benzene Organic Chemistry Amide Diamine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


  1. 1.
    B. N. Dolgov, N. P. Kharitonov, and M. G. Voronkov, ZhOKh,24, 678, 1954.Google Scholar
  2. 2.
    H. H. Reynolds, L. A. Bigow, and C. A. Kraus J. Am. Chem. Soc.,51, 3067, 1929.Google Scholar
  3. 3.
    C. A. Kraus and W. K. Nelson, J. Am. Chem. Soc.,56, 195, 1934.Google Scholar
  4. 4.
    N. S. Nametkin, V. N. Perchenko, and L. G. Batalova, DAN,158, 660, 1964.Google Scholar

Copyright information

© The Faraday Press, Inc. 1969

Authors and Affiliations

  • N. S. Nametkin
    • 1
  • E. S. Vasil'eva
    • 1
  • V. N. Perchenko
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisAS USSRMoscow

Personalised recommendations