Abstract
A study is made of the liquid phase hydrogenation ofα-(α′-furyl)-andα-(α′-thienyl)-β-nitroethylenes over Pd black. It is shown that the nature of the substituent (phenyl, furyl, thienyl) does not affect the mode of addition of the hydrogen to the nitrovinyl group. Conditions are found for catalytic synthesis of high yields of heterylacetaldehyde oximes from nitroalkenes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
L. Kh. Freidlin, E. F. Litvin, and V. M. Chursina, DAN,155, 1144, 1964.
A. P. Terent'ev and R. P. Gracheva, ZhOKh,32, 2231, 1962.
R. T. Gilsdorf and F. F. Nord, J. Org. Chem.,15, 807, 1950.
R. Takamota, J. Pharm. Soc. Japan.,48, 136, 1928.
L. Kh. Freidlin, E. F. Litvin, and V. M. Chursina, Kinetics and Catalysis [in Russian], 1967 (in press).
E. B. Maxted, Advances in Catalysis,3, 129, 1951.
L. Horner, H. Renter, and E. Hermann, Lieb. Ann.,660, 1, 1962.
D. V. Sokol'skii, Hydrogenation in Solution [in Russian], Alma-Ata, 1962.
O. Schales, Chem. Ber.,68, 1579, 1935.
Z. N. Nazarova, ZhOKh,24, 275, 1954.
W. J. King and F. F. Nord, J. Org. Chem.,14, 405, 1949.
V. M. Chursina, E. F. Litvin, and L. Kh. Freidlin, ZhAKh,21, 3, 365, 1966.
V. Asahina and A. Fujita, J. Pharm. Soc. Japan,490, 1084, 1922.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Freidlin, L.K., Litvin, E.F. & Chursina, V.M. Hydrogenation of heterocyclic analogs of β-nitrostyrene over palladium catalyst. Chem Heterocycl Compd 3, 14–17 (1967). https://doi.org/10.1007/BF00944247
Issue Date:
DOI: https://doi.org/10.1007/BF00944247