Abstract
Conditions of the addition of β-diketones of different structure to organosilicas were studied and the characteristic features of the course of the reactions were revealed.
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Yu. Nizel'skii and T. E. Lipatova, “Metal β-diketonates as catalysts of chemical reactions,” in: Problems of Chemistry and Use of Metal β-Diketonates [in Russian], Nauka, Moscow (1982), pp. 213–234.
V. M. Peshkova, “Use of β-diketonates for separating and concentrating of elements,” in: Problems of Chemistry and Use of Metal β-Diketonates [in Russian], Nauka, Moscow (1982), pp. 203–211.
K. G. Allum, R. D. Hanrock, I. V. Howell, et al., “Supported transition metal complexes,” J. Organomet. Chem.,87, No. 2, 203–216 (1975).
Yu. I. Ermakov, “Certain trends in synthesis and study of catalytic properties of transition metal complexes immobilized on silica gel,” in: Recent Problems of Science of Catalysis [in Russian], Institute of Catalysis, Siberian Branch, Academy of Sciences, Novosibirsk (1978), p. 91.
G. V. Lisichkin, G. V. Kudryavtsev, V. M. Ivanova, and V. N. Figurovskaya, “Complexforming mineral sorbents for chromatography,” Zh. Vses. Khim. Ova. Am. D. I. Mendeleeva,24, No. 3, 294–296 (1979).
V. V. Skopenko, T. P. Lishko, T. A. Sukhan, and A. K. Trofimchuk, “Acetylacetonate complexes of transition metals on SiO2 surface,” Ukr. Khim. Zh.,46, No. 10, 1026–1032 (1980).
V. A. Tertykh, L. A. Belyakova, and T. P. Kolotusha, et al., “Inorganic sorbents based on silica with chemically immobilized nitrogen- and oxygen-containing organic ligands for absorbing transition metal ions,” in: Chemistry and Technology of Inorganic Sorbents [in Russian], Izd. Akad. Nauk Turkmen SSR, Ashkhabad (1982), pp. 68–69.
L. A. Belyakova, V. G. Ivanova, T. P. Kolotusha, et al., “Method of preparation of sorbent,” Inventor's certificate No. 1031498 (USSR); Byull. Izobr., No. 28 (1983).
L. A. Belyakvoa, T. P. Kolotusha, and V. A. Tertykh, “Immobilization of a series of nitrogen- and oxygen-containing ligands on silica surface,” Adsorbtsiya Adsorbenty, No. 12, 3–12 (1984).
Yn. I. Ermakov, V. A. Zakharov, and B. N. Kuznetsov, Immobilized Complexes on Oxide Carriers [in Russian], Nauka, Novosibirsk (1980).
G. Becker, Introduction to Electronic Theory of Organic Reactions [Russian translation], Mir, Moscow (1977).
N. S. Zefirov, T. S. Kuznetsova, S. I. Kozhushkov, et al., “Cycloalkylation by α,ω-dibromides of compounds containing an activated methylene group as a method of synthesis of 1,1-disubstituted cycloalkanes,” Zh. Org. Khim.,29, No. 3, 541–545 (1983).
A. Turney, Modern Organic Chemistry [Russian translation], Vol. 2, Mir, Moscow (1981).
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 5, pp. 631–634, September–October, 1985.
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Belyakova, L.A., Kolotusha, T.P., Tertykh, V.A. et al. Characteristic features of reaction of certain derivatives of β-diketones with surface of organosilicas. Theor Exp Chem 21, 604–607 (1985). https://doi.org/10.1007/BF00944104
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DOI: https://doi.org/10.1007/BF00944104