Summary
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1.
The dipole moments of seven organosilicon compounds were measured.
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2.
It was found that 1,2-bistrimethylsilyl-, 1,2-bistriethylsilyl-,and 1,2-bistrichlorosilyl ethylenes have trans-configurations.
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3.
The presence of alternating polarity was detected in the compounds (CH)3SiCH2C6H4COCH3-p and (CH3)3SiCH2CH2C6H4COCH3-p
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4.
The effect of the silicon atom on a substituent diminishes with lengthening of the hydrocarbon chain.
Literature cited
G. N. Kartsev, Ya. K. Syrkin, V. F. Mironov, and E. A. Chemyshev, Doklady Akad. Nauk SSSR122, 99(1958).
K. Fajans, Chem. and Engng. News27, 900 (1949).
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Kartsev, G.N., Syrkin, Y.K. Dipole moments of some organosilic on compounds. Russ Chem Bull 9, 348–349 (1960). https://doi.org/10.1007/BF00942920
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DOI: https://doi.org/10.1007/BF00942920