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Action of hydrazine and phenylhydrazine on dialkylthioborinic esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Dialkylthioborinic esters react with hydrazine and with phenylhydrazine with formation, respectively, of 1,2-bisdialkylborinohydrazines and 1-dialkylborino-2-phenylhydrazines.

  2. 2.

    When heated with dialkylthioborinic esters, 1-dialkylborino-2-phenylhydrazines react with formation of 1,2-bisdialkylborino-1-phenylhydrazines.

  3. 3.

    With hydrazine,1,2-bisdialkylborinohydrazines form crystalline complexes which decompose when heated.

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Literature cited

  1. B. M. Mikhailov and Yu. N. Bubnov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 172 (1959).

  2. B. M. Mikhailov, V. A. Vaver, and Yu. N. Bubnov, Dgoklady Akad. Nauk SSSR126, 579 (1959).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    B. M. Mikhailov & Yu. N. Bubnov

Authors
  1. B. M. Mikhailov
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  2. Yu. N. Bubnov
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Mikhailov, B.M., Bubnov, Y.N. Action of hydrazine and phenylhydrazine on dialkylthioborinic esters. Russ Chem Bull 9, 340–342 (1960). https://doi.org/10.1007/BF00942917

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  • DOI: https://doi.org/10.1007/BF00942917

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