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Transformation of 1-hexene under the action of carbon monoxide and hydrogen over a cobalt catalyst

  • N. I. Ershov
  • Ya. T. Éidus
  • V. R. Erokhina
Brief Communications

Summary

  1. 1.

    A study was made of the effect of a high concentration of carbon monoxide on the course of the formation of hydrocarbons from 1-hexene, hydrogen, and carbon monoxide.

     
  2. 2.

    When the H2: CO ratio in the original vapor-gas mixture is changed from 6 to 2.2, the yield of higherboiling hydrocarbons is reduced only slightly, but the formation of lower-boiling hydrocarbons is almost completely suppressed.

     
  3. 3.

    The effect of an increased concentration of carbon monoxide in reactions in which propene or 1-butene take part is different from its effect in the reaction with 1-hexene.

     

Keywords

Hydrogen Cobalt Hydrocarbon Propene Carbon Monoxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    Ya. T. Éidus, N. I. Ershov, and E. M. Terent'eva, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk,882 (1954).Google Scholar
  2. 2.
    Ya. T. Éidus, N. D. Zelinskii, K. V. Puzitskii, and N. I. Ershov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 145 (1952).Google Scholar
  3. 3.
    A. J. Van Pelt, Jr. and J. P. Wibaut, Rec. trav. chim.60, 55 (1941).Google Scholar
  4. 4.
    N. I. Ershov and Ya. T. Éidus, Doklady Akad. Nauk-SSSR115, 1126 (1957);119, 1062 (1958).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1961

Authors and Affiliations

  • N. I. Ershov
    • 1
  • Ya. T. Éidus
    • 1
  • V. R. Erokhina
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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