Summary
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1.
Some properties of p-(trimethylsilyl)benzaldehyde were studied. It gives characteristic qualitative reactions of carbonyl compounds (silver mirror and reaction with Schiff's reagent) and freely gives addition and condensation reactions with sodium bisulfite, 2,4-dinitrophenylhydrazine, semicarbazide, hydroxylamine, ammonia, and aromatic amines.
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2.
The bisulfite compound, carbazone, and oxime of p-(trimethyisilyl)benzaldehyde were prepared for the first time, as also were 4,4%4′'-tristrimethylsilylhydroberizamide and N-p-(trimethylsilyl)benzylideneaniline.
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3.
It was shown that it is possible to prepare silicon-containing dyes of the triphenylmethane series.
Literature cited
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Chem. Abstrs.48, 624 (1954).
C. A. Burkhard, J. Amer. Chem. Soc.68, 2103 (1946).
K. Bauer, Analysis of Organic Compounds [Russian translation] (IL, 1953).
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Dolgov, B.N., Glushkova, N.E. & Kharitonov, N.P. Some properties of p-(trimethylsilyl)benzaldehyde. Russ Chem Bull 9, 319–321 (1960). https://doi.org/10.1007/BF00942911
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DOI: https://doi.org/10.1007/BF00942911