Summary
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1.
A detailed study was made of the Grignard reaction with esters of cis- and trans-1,2-cyclahexanedicarboxylic acids.
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2.
1,2-Bis(diphenylmethylene cyclohexane and diisopropylidenecyclohexane, and also their cyclobutane analogs, do not undergo diene condensation with maleic anhydride and with benzoquinone.
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3.
The Reformatsky reaction with 3,5-dimethyl-2-cyclopenten-1-one leads to 2,4-dimethyl-1,4-cyclo-pentadiene-1-acetic acids.
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Nazarov, I.N., Kuznetsov, N.V. Synthesis of dienes in which the double bonds are in fixed positions. Russ Chem Bull 9, 236–242 (1960). https://doi.org/10.1007/BF00942896
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DOI: https://doi.org/10.1007/BF00942896