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Reactions of fluoro olefins

Communication 12. Reactions of chlorofluorobutenes with alcohols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The action of sodium alkoxides on 1,3,4,-tetrachloro-1,2,3,4-tetrafluoro-1-butene leads to the formation of 1,1,1-trialkoxy-4,4-dichloro-2,3,4-trifluoro-2-butenes.

  2. 2.

    When sodium alkoxides react with the linear dimer of chlorotrifluoroethylene, 3-alkoxy-4-chlorohexafluoro-1-butenes are formed. The linear dimer of chlorotrifluoroethylene is probably a mixture of 3,4-dichloro-hexafluoro-1-butene and 1,4-dichlorohexafluoro-2-butene, with a predominance of the latter.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    I. L. Knunyants, B. L. Dyatkin, L. S. German & E. P. Mochalina

Authors
  1. I. L. Knunyants
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  2. B. L. Dyatkin
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  3. L. S. German
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  4. E. P. Mochalina
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Knunyants, I.L., Dyatkin, B.L., German, L.S. et al. Reactions of fluoro olefins. Russ Chem Bull 9, 211–215 (1960). https://doi.org/10.1007/BF00942892

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  • DOI: https://doi.org/10.1007/BF00942892

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