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Journal of Applied Electrochemistry

, Volume 13, Issue 3, pp 307–315 | Cite as

High efficiency hypochlorite generation

  • P. M. Robertson
  • W. Gnehm
  • L. Ponto
Papers

Abstract

The oxidation of chloride ion at DSA anodes gives higher yields of hypochlorite than were obtained at Pt or graphite electrodes.It is also shown that the problem of hypochlorite reduction at the cathode in undivided cells can largely be overcome by use of a ‘reduced area’ cathode. These two improvements have both been included in a new cylindrical hypochlorite cell capable of a 70% conversion of a 0.048 mol. dm−3 NaCl solution to NaOCl with a production rate of 50 gh−1 ‘active chlorine’.

Keywords

Oxidation Chloride Physical Chemistry Graphite Chlorine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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Copyright information

© Chapman and Hall Ltd. 1983

Authors and Affiliations

  • P. M. Robertson
    • 1
  • W. Gnehm
    • 1
  • L. Ponto
    • 2
  1. 1.Technisch Chemisches Labor, ETHZurichSwitzerland
  2. 2.Politechnika WarsawPoland

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