Conclusions
Rhodium hydrocarboranes catalyze the isomerization of primary unsaturated alcohols to the corresponding aldehydes, and that of secondary unsaturated alcohols to the corresponding ketones.
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Literature cited
L. A. Yanovskaya and Kh. Shakhidayatov, Usp. Khim.,39, 1801 (1970).
G. E. Emerson and R. Pettit, J. Am. Chem. Soc.,84, 4591 (1962).
R. Damico and T. J. Logan, J. Org. Chem.,32, 2356 (1967).
R. W. Goetz and M. Orchin, J. Am. Chem. Soc.,85, 1519 (1963).
Y. Sasson and G. L. Rempel, Tetrahedron Lett., 4133 (1974).
P. A. Grieco, N. Nishizawa, N. Marinovic, and W. Y. Ehmann, J. Org. Chem.,41, 3020 (1976).
T. E. Paxen and M. P. Hawthorne, J. Am. Chem. Soc.,96, 4674 (1974).
L. I. Zakharkin and T. B. Agakhanova, Zh. Obshch. Khim.,47, 2396 (1977).
V. N. Yur'ev, Dissertation, Moscow (1975).
C. D. Hurd and W. H. Saunders, J. Am. Chem. Soc.,74, 5324 (1952).
R. Wilson, J. Chem. Soc., 56 (1945).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2833–2835, December, 1978.
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Zakharkin, L.I., Agakhanova, T.B. Isomerization of unsaturated alcohols by rhodium hydrocarboranes to aldehydes and ketones. Russ Chem Bull 27, 2531–2533 (1978). https://doi.org/10.1007/BF00941122
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DOI: https://doi.org/10.1007/BF00941122