Conclusions
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1.
Perfluoro-2-azapropene reacts with phenylmagnesium bromide to give the vinylic substitution product, namely 1-phenylperfluoro-2-azapropene.
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2.
The reaction of perfluoro-2-azapropene with alkylmagnesium halides led to the isolation of the hydrolysis products of the 1-alkylperfluoro-2-azapropenes, namely the trifluoromethylamides of the corresponding carboxylic acids.
Literature cited
A. F. Gontar', N. A. Til'kunova, É. G. Bykhovskaya, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2379 (1977).
N. A. Til'kunova, A. F. Gontar', Yu. A. Sizov, É. G. Bykhovskaya, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2381 (1977).
L. A. Rozov, L. S. German, Yu. A. Zeifman, Yu. A. Cheburkov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 741 (1974).
I. L. Knunyants, L. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 221 (1960).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2820–2821, December, 1978.
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Til'kunova, N.A., Slota, S.I., Gontar', A.F. et al. Reaction of perfluoro-2-azapropene with organomagnesium compounds. Russ Chem Bull 27, 2518–2519 (1978). https://doi.org/10.1007/BF00941116
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DOI: https://doi.org/10.1007/BF00941116